Bracton Industries (NSW) Pty. Ltd.

ACN 003 060 160
P.O. Box 386,   Brookvale   NSW   2100,
Australia


Section 1: Identification of the Material and Supplier
Product Name:    Propylene Glycol Inhibitor (Formally Ice Bank Preservative)

Other Names:     Dilute aqueous solution of mixed preservatives.

Proper shipping name (ADG Code):   None.

Recommended use: As a preservative for propylene glycol machines. Dilute and
                 use as directed on the product label.

Supplier:        Bracton Industries (NSW) Pty. Ltd.,
                            ACN: 003 060 160
                 50 Chard Road, BROOKVALE   NSW  2100, Australia
                 Tel: +61 2 9938 1800        Fax: +61 2 9905 0979
                 Emergency Tel:    Not available
Section 2: Hazards Identification
Not classified as hazardous according to criteria of Worksafe
Australia.

Non-dangerous goods.

Risk Phrases:    None.

Safety Phrases:  S: 25   Avoid contact with eyes.
Section 3: Composition/Information on Ingredients
Ingredients:
     Mixed preservatives                                    < 2 %
     Water                         [7732-18-5]         to   100 %
Section 4: First Aid Measures
     For advice, contact a Poisons Information Centre (Phone  131126)
or a doctor.

     Swallowed:  Do not induce vomiting.

     Skin:       Remove contaminated clothing and wash skin thoroughly.

     Eyes:       Hold eyes open, flood with water for at least 15
                 minutes and seek medical advice.

     Inhaled:    Remove from exposure.

First Aid facilities:
     Recommended:        Hand wash basin.

Advice to Doctor:
      Product is a very dilute aqueous solution of mixed preservatives.
      May cause mild eye irritation. Contact Poisons Information
      Centre.

Aggravated medical conditions:
     None known.
Section 5: Fire Fighting Measures
HAZCHEM Code:            None assigned.

Extinguishant:           Water.

Risk of violent reaction or explosion:       No.

Products of combustion:  Water vapour, traces of oxides of nitrogen.

Protective Equipment:    Breathing apparatus and protective gloves for
                         fire only.
Section 6: Accidental Release Measures
Emergency Procedures:
     Contain.
     Prevent spillages from entering natural waters.

For large spills:
     Contain spillage using sand or earth. Transfer liquid and solids
     to suitable container. Treat residues as for small spillage.

For small spills:
     Mop up with plenty of water and run to waste, diluting greatly
     with running water, or absorb on inert absorbent, transfer to
     suitable container and arrange removal by disposals company. Wash
     site of spillage thoroughly with water and detergent.
Section 7: Handling and Storage
Precautions for safe handling:
     Avoid contact with skin and eyes.

Conditions for safe storage:
     Store in a cool, well ventilated place, out of reach of children.
     Large quantities should be stored in a bunded area. Store in
     original container. Keep container tightly closed and out of
     direct sunlight. Protect from physical damage. Clean up all spills
     and splashes promptly; avoid secondary accidents.

Incompatibles:
     Oxidising agents, acids.
Section 8: Exposure Controls/Personal Protection
National Exposure Standards:
     ES-TWA:             None assigned.

     ES-STEL:            None assigned.

     ES-PEAK:            None.

     Notations:          None.

Biological Limit Values:           No data.

Engineering Controls:
     Ensure adequate ventilation (same as outdoors) when using.
     If handling industrial quantities or if aerosol risk exists,
     consider local mechanical exhaust/extraction to keep airborne
     contamination as low as possible.

Personal Protective Equipment:
      Avoid contact with skin and eyes. Personal protection to be
      selected from those recommended below, as appropriate to mode of
      use, quantity handled and degree of hazard:-
      Normal Use:
             Eye/face protection
             Gloves, rubber or plastic.
      Industrial Quantities:
             Face shield or safety glasses
             Gloves, rubber or plastic
             Overalls.
Section 9: Physical and Chemical Properties
     Appearance:         Clear, pale pink to brown, mobile liquid.
     Odour:              None.
     pH:                 Alkaline.
     Vapour Pressure:    23 hPa @ 20 °C
     Vapour Density:     No data.
     Boiling Point:      100 °C
     Melting Point:      No data.
     Volatiles:          99 %
     Volatile Organic Compounds (VOC):       None.
     Evaporation Rate:   No data.
     Solubilities:       Miscible with water in all proportions.
     Specific Gravity/Density:     1 g/mL @ 20 °C
     Flash Point:        None.
     Flammable Limits:   None.
     Dust Explosion:     Not applicable.
     Auto-ignition Temperature:    No data.

Other Information:
     Incompatible with acids. May form a sediment on long storage -
     shake well before use. Slippery when spilled.
Section 10: Stability and Reactivity
Chemical Stability:      Stable under normal conditions.

Conditions to Avoid:     Incompatible materials.

Incompatible Materials:  Acids, oxidising agents.

Hazardous Decomposition Products:  Oxides of nitrogen.

Hazardous Reactions:     None known.
Section 11: Toxicological Information
Health Effects:
             No data available for the mixture.  Information presented
      relates to individual ingredients.

Acute:       Swallowed:    May cause gastric upset, nausea and possible
                           vomiting.

             Skin:         Prolonged contact may lead to mild
                           irritation.

             Eyes:         May cause mild irritation.

             Inhaled:      An unlikely route, owing to the low
                           volatility of ingredients.

Chronic:     Repeated skin contact may lead to irritation.

LD50:        Preservative #1                    656 mg/kg oral, rat.
                                                683 mg/kg oral, mouse.
                                                500 mg/kg oral, cat.

             Preservative #2                    560 mg/kg oral, rat.
                                                615 mg/kg oral, mouse.
Section 12: Ecological Information
Ecotoxicity:                       May be harmful to aquatic organisms.

Persistence and degradability:     No data.

Mobility:                          Readily transported by water.

Environmental Fate:                No data.

Bioaccumulative potential:         No data.

Other adverse environmental effects:         No data.
Section 13: Disposal Considerations
     The generator of any wastes from this product is responsible for
its proper classification, transport and disposal.

     Consult appropriate local and State regulations.

Disposal methods and containers:
     Avoid disposal to natural waters or the environment.

Special precautions for landfill or incineration:
     Not suitable for landfill.
Section 14: Transport Information
UN Number:                         None assigned.

UN Proper shipping name:           None.

Class and subsidiary risk:         None.

Packaging group:                   None.

Special precautions for user:      None.

HAZCHEM Code:                      None assigned.

     Material for export:          No data.
Section 15: Regulatory Information
Poisons (SUSDP):         Not a scheduled poison.

Dangerous Goods:         Not dangerous goods.

Carcinogen:      Australia         IARC      NTP       
                 No.               No.       No.       

Agricultural and Veterinary Chemicals Act:   No data.

Australian Inventory of Chemical Substances (AICS):    Listed.

Other National/International Regulations:    No data.
Section 16: Other information
Date of MSDS preparation/update:   July 2004

Abbreviations:
     NOHSC - National Occupational Health and Safety Commission.
     ACGIH - American Conference of Governmental Industrial Hygienists.
     MAK -   Maximum workplace concentration - Germany,
             (maximale Arbeitsplatzkonzentration)
     IARC -  International Agency for Research on Cancer (France).
     NPT -   National Toxicology Program (USA).
     HSE -   Health and Safety Executive (United Kingdom).

Literature references:

Available Sources of Data:
National Code of Practice for the Preparation of Material Safety Data
Sheets 2nd Edition [2011(2003)] - NOHSC.
Australian Dangerous Goods Code.
Standard for the Uniform Scheduling of Drugs and Poisons - AHMAC.
Exposure Standards for Atmospheric Contaminants in the
Occupational Environment [1003]- NOHSC.
List of Designated Hazardous Substances [10005] - NOHSC.
Merck Index - Merck Inc.
Sax's Dangerous Properties of Industrial Materials - Lewis.
Handbook of Toxic and Hazardous Chemicals and Carcinogens - Sittig.
Handbook of Reactive Chemical Hazards - Bretherick.
Hawley's Condensed Chemical Dictionary - Wiley Interscience.
AUSREG's Chemical Data Package for PCs - AUSREG Consultancy.

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